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sulfur hexafluoride : ウィキペディア英語版
sulfur hexafluoride

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Sulfur hexafluoride (SF6) is an inorganic, colorless, odorless, non-flammable, extremely potent greenhouse gas which is an excellent electrical insulator.〔 has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. Typical for a nonpolar gas, it is poorly soluble in water but soluble in nonpolar organic solvents. It is generally transported as a liquefied compressed gas. It has a density of 6.12 g/L at sea level conditions, which is considerably higher than the density of air (1.225 g/L).
==Synthesis and reactions==
can be prepared from the elements through exposure of to . This was also the method used by the discoverers Henri Moissan and Paul Lebeau in 1901. Some other sulfur fluorides are cogenerated, but these are removed by heating the mixture to disproportionate any (which is highly toxic) and then scrubbing the product with NaOH to destroy remaining .
There is virtually no reaction chemistry for . A main contribution to the inertness of SF6 is the steric hindrance of the sulfur atom, whereas its heavier group 16 counterparts, such as SeF6 are more reactive than SF6 as a result of less steric hindrance (See hydrolysis example). It does not react with molten sodium, but reacts exothermically with lithium.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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